However, the problem with this technique with respect to the Lanthanide elements is the fact that the 4f and 5d sub-shells have very similar energy levels, which can make it hard to tell the difference between the two.Īnother important feature of the Lanthanides is the Lanthanide Contraction, in which the 5s and 5p orbitals penetrate the 4f sub-shell. The technique used is based on the fact that each line in an emission spectrum reveals the energy change involved in the transition of an electron from one energy level to another. The electron configurations of these elements were primarily established through experiments. This means that the electron start to fill the 4f sub-shell before the 5d sub-shell. After Lanthanum, the energy of the 4f sub-shell falls below that of the 5d sub-shell. These elements are different from the main group elements in the fact that they have electrons in the f orbital. Similarly, the Lanthanides have similarities in their electron configuration, which explains most of the physical similarities. Ionic complexes undergo rapid ligand-exchange.A preference for more electronegative elements (such as O or F) binding.Tendency to decreasing coordination number across the series.Adoption of coordination numbers greater than 6 (usually 8-9) in compounds.They can also have an oxidation state of +2 or +4, though some lanthanides are most stable in the +3 oxidation state.Adoption mainly of the +3 oxidation state.Similarity in physical properties throughout the series.These characteristics include the following: Like any other series in the periodic table, such as the Alkali metals or the Halogens, the Lanthanides share many similar characteristics. The term Lanthanides was adopted, originating from the first element of the series, Lanthanum. However, this is can be misleading since the Lanthanide elements have a practically unlimited abundance. These elements were first classified as ‘rare earth’ due to the fact that obtained by reasonably rare minerals. The rest of the elements were later separated from the same mineral. Later, Moseley used an x-ray spectra of the elements to prove that there were fourteen elements between Lanthanum and Hafnium. In 1803, Berzelius and Klaproth secluded the first Cerium compound. In 1794, Professor Gadolin obtained yttria, an impure form of yttrium oxide, from the mineral. This mineral, now known as Gadolinite, was later separated into the various Lanthanide elements. The Lanthanides were first discovered in 1787 when a unusual black mineral was found in Ytterby, Sweden.
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3/15/2024 0 Comments Purble place free unblockedHow to Play Watermelon Game Unblocked at School or Workplace Replay challenging levels to refine your strategies and achieve higher scores.Prioritize merging larger fruits to create valuable combos. Plan your moves carefully to prevent fruits from falling off the container.Tips and tricks to merge as many watermelons as you can Aim to create a watermelon to clear the level.Merge fruits of the same kind by moving them together.Use the controller's directional buttons and A button to control fruits.Select the game icon on the Switch home screen.Download and install Suika Game from the Nintendo eShop.Continue merging fruits until you achieve the ultimate goal – creating a watermelon.Strategically position fruits to prevent them from falling off the screen.Click and drag fruits of the same kind to merge them.How to Play Watermelon Game? Play Watermelon Game on PC Satisfying Transformations: Witness the transformation of fruits as they evolve into larger and more impressive varieties.Challenging Levels: Progress through increasingly intricate levels that test your puzzle-solving skills.Strategic Fruit Merging: Plan your moves carefully to maximize fruit merging opportunities.Physics-Based Gameplay: Experience the dynamic behavior of fruits as they interact and merge.Twitch, a popular streaming platform, witnessed a significant spike in Suika Game viewership, with millions of hours of content consumed each month Watermelon Game Features Notably, prominent figures like Japanese VTubers and artists like Ado embraced the game, generating a buzz around it. This surge can be attributed in part to the influence of content creators and streamers. Two years after its debut, Watermelon Game experienced a meteoric rise in popularity in September 2023. This marked the game's transformation into the Suika Game or Watermelon Game. Watermelon Game traces its roots to a Chinese web game called " Synthetic Big Watermelon." However, it wasn't until December 9, 2021, when Aladdin X introduced it to the Nintendo eShop in Japan, that it gained worldwide recognition. Watermelon Game Overview History of Watermelon Game 3/15/2024 0 Comments Mahjong titan free online gameUpon winning the game, you are rewarded a star for solving the puzzle you were playing. There is no time limit, but if you’d like more challenge, you can enable the timer feature in the settings. You win the game when all tiles are removed. Feel free to use a hint or shuffle button if you can’t find any. We recommend starting your first game with the classic Turtle layout.īegin by looking for two open tiles that can be removed. Our game offers you more than a hundred original layouts to solve. The shape of the puzzle significantly impacts the game’s difficulty, and some puzzles will be easier to solve than others. When the game starts, tiles get arranged into a pyramid-like shape with multiple layers stacked on one another, usually forming some figure. Tile can slide out to the left or right.įind examples in our detailed guide on how to play Mahjong Solitaire.
In addition, if there are physical scratches on the vehicle body, the livery will cover it elegantly. So, the use of livery is to beautify the appearance of a vehicle. Everyone uses the exact same shirt design, pants, drums, and even car designs! Isn’t that amazing? Just imagine, when there is a carnival convoy event that is so exclusive. There are 117 files Yudistira HD bus livery! UsabilityĪs i mentioned above, a livery can represent a particular group or community, so that it can give a proud impression. Well, in the Bus Simulator Indonesia game, you can download the livery that I have prepared this time. After clicking buy successfully, you can switch to use it in the garage. The bus can be forced to buy without deducting money. In fact, you can also make livery according to your wishes and motives that have nothing to do with any identity, it’s all up to you. The driver skin can be forced to buy without deducting money, just select the driver you want to use and click hire. This motif can be adapted to a particular organization, group or community. In the real world, you can see the Redbull car design is so cool with a motif that is so striking and describes a challenging terrain, it can also be called as livery. Kami sadar kalau game ini masih culun (baca: dalam tahap awal). Template Efek Rongsokan + Kaca Pecahįor those of you who don’t understand what livery is, livery is an element that can be installed as clothes on a vehicle such as a car, bus, to motorcycle.
3/15/2024 0 Comments Are js files minifiedThis file contains the list of bundles and some optional properties. After you create a bundle, a file named bundleconfig.json is added to the project. This menu is available for CSS and JS files. File Original Minified Gzip Min + Gzip jquery.js: 252881: 94840: 73775: 33656: drupal. By removing extraneous semicolons, comments, whitespace, along with using shorter variable functions and names, developers can create a more compact file size. Manually minifying JavaScript files is only possible for small files because it’s so time-intensive. Think of minification as refining Javascript code. It’s nearly impossible to minify all of the codes in large JavaScript files manually. Once you install the extension, a new menu item is available in the solution explorer: It involves truncating all unnecessary characters of Javascript source code without impacting its usefulness and functionality. This extension relies on NUglify, a fork of the Microsoft Ajax Minifier, to minify CSS and JS. To remove the Node.js dependency, Mads Kristensen has written an extension for Visual Studio for minifying files: BundlerMinifier. Finally, every developer must install Node.js on their computer to build the project. For instance, creating a new project is longer because of installing the Node.js dependencies (about 1500 files in node_modules). However, using Node.js and gulp has also negative effects. This tool is widely used by front-end developers to automate build tasks. If you decide to try another minification plugin, make sure your new choice also drops dead code as described in the tree. Note that while the TerserPlugin is a great place to start for minification and being used by default, there are other options out there: ClosureWebpackPlugin. In the preview version of ASP.NET Core, the web site template uses Gulp to generate the min files. Webpack v4+ will minify your code by default in production mode. Now we understand why we should bundle and minify stylesheets and JavaScript files, let's see how we can do that with Visual Studio and ASP.NET Core. If you are not familiar with HTTP/2, you should read this blog post from 2 members of the IIS team. With HTTP/2, this is less important, mainly if you can take advantage of Server push (not currently supported in. This reduces the number of requests needed to display a web page, and so the loading time. Minifying consists of reducing the size of the JavaScript and Stylesheet files by removing comments, spaces, merging CSS rules, shortening variable/function names, replacing true by !0, and lots of advanced techniques.īundling consists of combining multiple files. Today, I'll stay on improving performance with bundling and minifying stylesheets and JavaScript files. The second is about reducing the size of the server response with gzip compression. The first one was about caching files to ensure the browser download them only once. Oh yes, minifying could also remove comments.In the last two posts, I wrote about improving ASP.NET Core web site performance. If you don't want to give away your pristine source code with comments and all, minifying and obfuscating are both good tactics to use. Although there are other tools that can further obfuscate your code. If you depend on many other libraries, they can add up to many more lines of code and could enjoy the help of a minifier.Ī minifier can also obfuscate your code a little bit. But when you start to go into millions of lines of code, those gains get more noticeable.Īlso it has effects on your dependencies. With a small script it wouldn't matter much. The JavaScript parser used by the browsers could read the minified source code slightly faster. The Closure tools by Google seem more capable of going into more advanced minification levels. Sometimes they can tell exactly how variables are used then they could try to rename some of the variables to shorter names as well.ĭifferent tools provide different levels of minification. The least they can do is to remove the unnecessary white spaces. It depends on the settings used by the minifier. 3/15/2024 0 Comments Tv series virgin river castHowever, the show jumped the shark from the first episode and I'm reminded of it every show. Everyone has an unrealistic drama going on in their lives. There is never a scene without a smooch and an "I love you", along with an excess of nosiness disguised as caring about the other person when they are all really self-absorbed narcissists desperate to turn the conversation to themselves and their own neediness. I watch this mainly because my wife likes it, but for me it's too schmaltzy. Rated 4.5/5 Stars Rated 4.5 out of 5 stars If Virgin River was a real place, I WOULD MOVE THERE RIGHTAWAY!!! I like that the whole show, although too soapy for some, focuses on community support and gives the viewers a sense of security and comfort. There's such a cosy atmosphere that makes you feel that ideal communities exist and people are still good. and Found Mel contemplates being a temporary foster parent to Chloe while grappling with her own grief Jack works to convince her to stay in Virgin River.ĭetails Episode 4 Aired A Wounded Heart Hope's health scare prompts a difficult conversation with Doc Charmaine asks Mel uncomfortable questions Paige has secrets.ĭetails Episode 5 Aired Under Fire Mel and Jack, under pressure, respond to a medical emergency on a remote illegal pot farm Charmaine and Hope exchange words.ĭetails Episode 6 Aired Let's Mingle Mel gets a surprise visitor just in time for the town's big dance party Jack continues to have flashbacks from his time in the military.ĭetails Episode 7 Aired If Truth Be Told Preacher happens upon a secret Mel's memories threaten to overwhelm her Jack has a sincere talk with Charmaine regarding their relationship.ĭetails Episode 8 Aired Into the Light A storm causes a power outage in town and everybody gets together at Jack's bar Mel grapples with her revelation Preacher investigates Paige.ĭetails Episode 9 Aired Everybody Has a Secret Hope urges Jack to read Charmaine's letter Preacher confronts Paige with his new knowledge Doc and Mel work together on a pressing case.ĭetails Episode 10 Aired Unexpected Endings Charmaine tells a stunned Jack to make a decision while Mel is left reeling and Hope is filled with guilt Paige opens up to Preacher.Įasy and enjoyable to watch. Virgin River revolves around the life of Melinda "Mel" Monroe, a nurse practitioner and midwife who moves to Virgin River from Los Angeles in search of a fresh start after experiencing personal tragedies.Previous Episode 1 Aired Carry On When nurse practitioner Mel moves to a remote town in Northern California seeking a new life, she is startled by the welcome she receives.ĭetails Episode 2 Aired Lost After finding an abandoned baby on Doc Mullins' doorstep, Mel and her boss argue over whether to call Social Services or find the newborn's mother.ĭetails Episode 3 Aired. How many seasons of Virgin River are on Netflix?įive. The show is set in a picturesque and remote northern California town called Virgin River. Sarah Dugdale is known for "Mystery 101" and has guest-starred in shows like "Supernatural" and "Arrow."Ĭonnie: Nicola CavendishConnie, a friend of Hope and Connie, runs Virgin River's general store and is a member of the local.įAQs: What is Virgin River on Netflix?"Virgin River" is a popular Netflix series based on the bestselling novels by Robyn Carr. Lizzie: Sarah DugdaleLizzie, a teenage troublemaker sent to live with her aunt Connie, embarks on a secret relationship with Ricky. Grayson Gurney has starred in teen comedy series "Game On." Ricky: Grayson GurnseyRicky, the busboy at Jack's bar with dreams of becoming a Marine, forms a secret relationship with Lizzie. Kai Bradbury has appeared in "The Man in the High Castle," "Altered Carbon," and "Supernatural." Mark Ghanimé, known for "Helix" and "Reign," takes on the role.ĭenny Cutler: Kai BradburyDenny Cutler, Doc's grandson, makes his first appearance in Season 3. Cameron Hayek, the new doctor at Doc's surgery, is introduced in Season 4. Marco Grazzini has appeared in "Kim's Convenience," "Heroes Reborn," and "The Flash." Dr. Mike Valenzuela: Marco GrazziniMike Valenzuela, an ex-Marine friend of Jack's, is a police detective. Lauren Hammersley, known for "Orphan Black" and "Mr. Jenny Cooper, who plays Mel, has a history in "24" and appeared in "Grey's Anatomy," "The Outer Limits," and "CSI: Miami."Ĭharmaine Roberts: Lauren Hammersle圜harmaine's romantic involvement with Jack leads to complex dynamics. Joey Barnes: Jenny CooperJoey Barnes is Mel's older sister living in Los Angeles. Zibby Allen's previous work includes "Grey's Anatomy," "Bates Motel," "The Exorcist," and "The Flash." She's also appeared in "Chucky" and "Arrow."īrie Sheridan: Zibby AllenBrie Sheridan, Jack's younger sister and a lawyer, adds depth to the story. Lexa Doig, known for "Andromeda" and "Jason X," takes on the role. Paige: Lexa DoigPaige runs a bakery truck and captures Preacher's curiosity. If you want to download apps on your iPhone without the App Store but prefer to avoid jailbreaking your device, another method you can explore is using external sources. It’s important to weigh the benefits against the potential risks and drawbacks before deciding to jailbreak your iPhone. While jailbreaking can provide significant flexibility and customization options, it is a decision that should be carefully considered. Additionally, future iOS updates may render your jailbreak obsolete, requiring you to re-jailbreak your device to regain access to your apps. It’s important to note that jailbreaking your device can void your warranty and potentially compromise its security. These apps can range from tweaks and modifications to fully-fledged applications. Search and install apps: With the package manager installed, you can now search for and install apps that are not available on the App Store.These package managers act as alternative app stores, allowing you to browse and install apps from unofficial sources. Install a package manager: After successfully jailbreaking your device, you will need to install a package manager such as Cydia or Sileo.This typically involves connecting your iPhone to your computer and running the jailbreak software. Follow the instructions: Once you have selected a jailbreak tool, carefully follow the instructions provided by the tool’s developers.Backup your device: Before proceeding with the jailbreak process, it’s essential to back up your iPhone to ensure that your data is safe in case something goes wrong during the jailbreak process.It’s crucial to research and identify a reliable jailbreak tool that is compatible with your device and iOS version. Research and choose a jailbreak tool: There are several jailbreak tools available, each supporting different iOS versions and device models.Here’s an overview of how to use jailbreak to download apps on your iPhone: However, it’s important to note that jailbreaking your device comes with its own set of risks and considerations. Jailbreaking opens up a world of possibilities, as it allows you to download and install apps that are not available on the App Store. By jailbreaking your device, you gain access to the root file system, allowing you to modify and customize various aspects of your iPhone, including installing apps from unofficial sources. In the world of iOS, jailbreaking is a term that refers to the process of removing software restrictions imposed by Apple on your iPhone. However, it’s crucial to stay vigilant and only download apps from trusted sources to ensure the security and integrity of your device. Keep in mind that you may need to adjust your device’s settings to allow installations from unknown sources.īy utilizing third-party app stores, you can enjoy a wider selection of apps that may not be available through the App Store. This will enable you to access their library of apps and download them directly onto your device. Once you have identified a third-party app store that suits your needs, you can proceed to download and install their app store application on your iPhone. Therefore, it’s important to exercise caution and research the reputation of the app store before downloading any apps. While these stores strive to provide safe and legitimate apps, there is always a risk of malware or malicious software slipping through the cracks. Using third-party app stores like these requires you to trust the sources of the apps you download. It is known for its user-friendly interface and the ability to download apps without needing to jailbreak your device. AppValley: AppValley offers a wide range of apps and games that are not available on the App Store.It features a user-friendly interface and supports multiple languages, making it easy to navigate and find the apps you’re looking for. TutuApp: TutuApp is another well-known third-party app store that provides a vast library of apps, including both free and paid options.It requires you to install a companion app on your computer, which then enables you to install apps directly on your device using your Apple ID. AltStore: AltStore is a unique app store that allows you to sideload apps on your iPhone without jailbreaking.Here are a few popular third-party app stores you can explore: These app stores provide an alternative platform for developers to distribute their apps outside of the official Apple ecosystem. One of the easiest ways to download apps on your iPhone without the App Store is by using third-party app stores. With that said, let’s dive into the different methods that can enable you to download apps on your iPhone without relying solely on the App Store. Therefore, proceed with caution and ensure that you understand the risks involved. It is important to note that some of these methods may void your device’s warranty or compromise its security. 3/14/2024 0 Comments Witch sigil for protectionMaking a sigil is a great way to give a physical form to your intentions and goals and is an incredibly powerful form of magick. Drawing it on paper also makes it easier to carry and conceal, particularly if you're in the broom closet. This makes them easier to destroy usually by burning either when activating them (more about this later) or when the magick is complete. They can be drawn, carved or burned into any kind of material, but usually they are simply drawn with a pen or pencil on a piece of paper. It’s one of my favourite kinds of magick and I'm fascinated by their power and simplicity. It’s a good example of Chaos Magick, where an affirmation, statement, word or name is converted to symbolic form which is charged with very specific intention and is an incredibly powerful form of magick. But please don’t let this alarm you! In modern day magick, like the kind this post is concerned with, sigils are used for personal matters such as attracting wealth, protection, healing, setting stronger boundaries and used to represent an intention or thought and have no connection to demonology or dark magick. A good example is The Lesser Key of Solomon, an anonymous grimoire of 72 sigils used to control 72 demons compiled in the late 1600s. The word ‘ sigil’ comes from the Latin word ‘ sigillum’ which means ‘seal’ and they played an important role in Medieval ceremonial magick, where symbols were used to raise and control a specific entity, like an angel or a demon. Even in a religious context, sigils have been used by many ancient civilisations stretching back millennia – good examples of this are the Christian cross and the Jewish Star of David. A sigil is a magickal sign or symbol that has been created to represent a particular intention or goal and have been used by Witches and occultists for centuries. 3/14/2024 0 Comments Grease movie production companyHe was also responsible for the opening of the Civic Theater in Chicago, where he underwrote ''The World of Carl Sandburg,'' with Bette Davis and Gary Merrill Tyrone Guthrie's production of ''Mary Stuart,'' starring Eva Le Gallienne, and Tennessee Williams's ''Garden District,'' with Cathleen Nesbitt and Diana Barrymore. His first venture was as one of the creators of the Playboy Penthouse Television series, which helped pave the way for Hugh Hefner's Playboy clubs. Carr attended Lake Forest College and entered show business after studying briefly at Northwestern University. That show's opening number featured a squeaky-voiced Snow White singing ''Proud Mary'' with the actor Rob Lowe, prompting legal action by the Walt Disney Company.Ī party-giver par excellence who favored ''large-man caftans'' during the 1970's, Mr.Carr once feted Truman Capote in an abandoned Los Angeles jail. He was perhaps just as renowned for his penchant for camp, most notably as the producer of the 1989 Academy Awards telecast. Carr was noted for his shrewd timing and keen nose for new talent. In a varied career that included stints as a publicist and manager, Mr. The cause was liver cancer, Ronni Chasen, a longtime friend, said. Production Budget: 6,000,000 (worldwide box office is 64.6 times production budget) Theater counts: 862 opening theaters/2,931 max. He was 62 and also had a home in Palm Springs, Calif. Allan Carr, the producer behind the popular movie musical ''Grease'' and the Tony Award-winning Broadway hit ''La Cage aux Folles,'' died on Tuesday at his home in Beverly Hills, Calif. 3/14/2024 0 Comments Sexy sniper girl anime hotShe is a leader who exudes integrity and strongly desires to marry. She does what she can to make the negative views of Kirigakure change. The sexiest Mizukage Mei Terumi is one of the most attractive characters in Naruto, without a doubt. As a result, he and Rachel make it out of the ordeal alive. Boy, do we need help… why is it always the cold-hearted characters that we like the most? Anyway, despite his cold personality he slowly warms up to a girl named Rachel Gardner. But, it is precisely his cold personality that makes some of us swoon over him. Isaac (Zack) Foster (Angels of Death)Ĭoming from Angels of Death, Zack Foster is one scary hottie. You can check 59+ BEST & Hottest Anime Guys (Husbando) or 21+ HOTTEST Manhwa Guys (Husbandos). BUT, if you’re more interested in seeing husbandos then we have an article right up your alley. So, try not to get a nosebleed when your favorite pops up! Relax and have some snacks to keep you busy while your eyes get busy on their own. That’s right folks! We’re putting husbandos and waifus together to finally see which anime character reigns supreme -at least in this list. We’re having the hottest male and female characters ranked to see which of these attractive characters can take the number one spot. Today, we’ve got 58 hottest anime characters on the list, and it ranges from brooding husbandos to dream waifus. Shion (That Time I Got Reincarnated as A Slime) Yukihira Soma (Food Wars! Shokugeki no Soma) Kambe Daisuki (The Millionaire Detective – Balance: UNLIMITED) Erina Nakiri (Food Wars! Shokugeki no Soma) Yoko Littner (Tengen Toppa Gurren Lagann) Alice Nakiri (Food Wars! Shokugeki no Soma) |
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